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排序方式: 共有1913条查询结果,搜索用时 15 毫秒
41.
Yujiro Watanabe Yusuke Moriyoshi Yasushi Suetsugu Toshiyuki Ikoma Takeshi Kasama Tadashi Hashimoto Hirohisa Yamada Junzo Tanaka 《Journal of the American Ceramic Society》2004,87(7):1395-1397
Type-A zeolite evenly covered with hydroxyapatite thin layers was prepared using hydrothermal treatment at 120°C for 8 h under autogenous pressure. The hydroxyapatite needlelike nanocrystals, 100–200 nm in diameter and 30 nm in thickness, were grown under the reaction between discharged Ca2+ ions from type-A zeolite and PO4 3− ions in (NH4 )3 PO4 solution. The preferential orientations of the c -axis of hydroxyapatite crystals perpendicular to a zeolite surface were observed using transmission electron microscopy. The crystal structure of type-A zeolite was not destroyed under the reaction, but the surface morphology was changed only with complete covering of scaly hydroxyapatite particles. 相似文献
42.
Yoshiyuki Sakamoto Tomoyoshi Motohiro Shinichi Matsunaga Kohei Okumura Tomoyuki Kayama Kiyoshi Yamazaki Toshiyuki Tanaka Yoshimi Kizaki Naoki Takahashi Hirofumi Shinjoh 《Catalysis Today》2007,121(3-4):217-225
The release and reduction of NOx in a NOx storage-reduction (NSR) catalyst were studied with a transient reaction analysis in the millisecond range, which was made possible by the combination of pulsed injection of gases and time resolved time-of-flight mass spectrometry. After an O2 pulse and a subsequent NO pulse were injected into a pellet of the Pt/Ba/Al2O3 catalyst, the time profiles of several gas products, NO, N2, NH3 and H2O, were obtained as a result of the release and reduction of NOx caused by H2 injection. Comparing the time profiles in another analysis, which were obtained using a model catalyst consisting of a flat 5 nmPt/Ba(NO3)2/cordierite plate, the release and reduction of NOx on Pt/Ba/Al2O3 catalyst that stored NOx took the following two steps; in the first step NO molecules were released from Ba and in the second step the released NO was reduced into N2 by H2 pulse injection. When this H2 pulse was injected in a large amount, NO was reduced to NH3 instead of N2.
A only small amount of H2O was detected because of the strong affinity for alumina support. We can analyze the NOx regeneration process to separate two steps of the NOx release and reduction by a detailed analysis of the time profiles using a two-step reaction model. From the result of the analysis, it is found that the rate constant for NOx release increased as temperature increase. 相似文献
43.
To obtain fundamental information about hydrogen transfer, the relationships between hydrogen donor ability and chemical structure of model compounds representing donor solvents is studied using gas chromatography,1H n.m.r. and computing calculation methods. The order of the model compounds in terms of the ability as donor solvent to release hydrogen is: decalin < tetralin < 1,2-dihydronaphthalene < < 1,4-dihydronaphthalene. This trend closely correlates with the difference in binding energies of the hydroaromatic compounds and their radicals, determined by intermediate neglect of differential overlap (INDO) calculation. Electron spin resonance spectroscopy (e.s.r.) confirms that radical species are created after heat-treatment of the donor compounds. The ability of model compounds representing coal to accept hydrogen is assessed from a comparison of the1H n.m.r. spectra. It is established that donor and acceptor efficacies are dependent upon chemical structure. 相似文献
44.
Wataru Sugimoto 《Electrochimica acta》2004,49(2):313-320
The pseudocapacitance of nanocrystalline RuO2 with BET surface area of 42 m2 g−1 was evaluated using a RuO2 modified Glassy Carbon (RuO2/GC) thin film electrode. The charge storage behavior of the RuO2/GC thin film electrode was studied from fast to slow scan cyclic voltammetry between various potential windows. The utilization of the thin film electrode method for nanocrystalline RuO2 with known specific surface area allowed a semi-quantitative understanding of the electric double-layer capacitance (Cdl), adsorption related charge (Cad), and the irreversible redox related charge (Cirr) per unit mass and surface area of RuO2. Comparison of the cyclic voltammograms between different voltage windows revealed that the contribution from Cirr is especially dominant below 0.4 V (versus RHE) at slow scan rates. 相似文献
45.
Stress distributions and deformation of adhesive butt joints are analyzed by an elastoplastic finite element method when the joints of similar and dissimilar shafts are subjected to external bending moments. The effects of the ratio of Young's modulus for the adherends to that for an adhesive and the effects of the adhesive thickness on the interface stress distribution are investigated. Joint strength is predicted by using the elastoplastic interface stress distributions. It is found that the singular stress at the edge of the interfaces increases with an increase of the ratio of Young's modulus. Measurement of strains in joints and experiments on joint strength were conducted. The numerical results are in fairly good agreement with the experimental results. It is observed that the joint strength for dissimilar shafts are smaller than those for similar shafts. A fracture of dissimilar adhesive up-bonded shafts occurred from the interface of the adherend with smaller Young's modulus. It is seen that joint strength increases as the adhesive thickness increases. 相似文献
46.
Prediction model of surface residual stress within a machined surface by combining two orthogonal plane models 总被引:2,自引:1,他引:2
Hiroyuki Sasahara Toshiyuki Obikawa Takahiro Shirakashi 《International Journal of Machine Tools and Manufacture》2004,44(7-8):815-822
The variation of surface residual stress within a machined surface layer caused by face turning was studied. The size of the tool’s corner radius and the feed rate affect residual stress. A process model using the finite element method is proposed and the mechanical effects of the corner radius and feed rate on a machined surface were discussed. When a tool with a small corner radius is used, surface residual stress perpendicular to the cutting direction becomes compression stress. As well, surface residual stress changes from tension to compression as the feed rate decreases. The process model consists of an orthogonal cutting simulation and an indentation-like simulation of a corner radius into a work piece surface. The simulated results show quantitative agreement with the residual stress measured experimentally. The integrity of the machined surface will be controlled more efficiently if the cutting conditions during finishing are determined with the proper consideration of the surface generating process. 相似文献
47.
Mutsumu Fukada Kiyotaka Kinoshita Toshiyuki Kajioka 《Journal of the Society for Information Display》2016,24(5):307-311
Abstract — This paper proposes a new process to manufacture cover glass that overcomes a strength trade‐off between the face and the edge. In the process, alkali barrier films are deposited on glass faces before an ion exchange process in order to control face stress properties without inhibiting the edge strengthening. As a demonstration of the process, alkali‐alumino‐silicate glass sheets with sputter‐deposited SiO2 films were chemically strengthened, and then their stress properties and strengths were investigated. As a result, thicker SiO2 films cause lower face DOL (depth of strengthened layer), and it is observed that the faces have lower DOL than the edges. In strength tests corresponding to major fracture modes of smartphone cover glass, specimens with 80–100 nm films have more balanced face performance and better edge impact strengths than the no‐film specimen. 相似文献
48.
A four-element retroreflector was designed for satellite laser ranging and Earth-satellite-Earth laser long-path absorption measurement of the atmosphere. The retroreflector consists of four symmetrically located corner retroreflectors. Each retroreflector element has curved mirrors and tuned dihedral angles to correct velocity aberrations. A genetic algorithm was employed to optimize dihedral angles of each element and the directions of the four elements. The optimized four-element retroreflector has high reflectance with a reasonably broad angular coverage. It is also shown that the genetic algorithm is effective for optimizing optics with many parameters. 相似文献
49.
Fumitaka Tsukihashi Toshiyuki Hatta Eiji Tawara 《Metallurgical and Materials Transactions B》1996,27(6):967-972
The deoxidation equilibrium of molten titanium and titanium-aluminum alloys saturated with solid CaO has been measured in the temperature range from 1823 to 2023 K. The equilibrium constant of reaction CaO (s)=Ca (mass pct in Ti,Ti-Al)+O (mass pct in Ti,Ti-Al) and the interaction parameter between calcium and oxygen were determined for Ti, TiAl, and TiAl3. The standard Gibbs energy of reaction for TiAl was obtained as follows: $$\Delta G^\circ = 279,000 - 103TJ/mol$$ The possibilities for the deoxidation of titanium and titanium-aluminum alloys by using calcium-based fluxes are discussed. 相似文献
50.
The Vertical Block–cyclic Distributed Parallel LU Factorization Method (VBPLU) is effectively processed on a distributed memory parallel computer. VBPLU is based on the two techniques, the block algorithm and the aggregation of communications. Since startup time dominates the data communication and the aggregation reduces communication isssues, the total performance has been much improved. Furthermore this method uses long vectors so that it is also advantageous on vector processors. In this paper, we have constructed a modeling of VBPLU using a simplified LogGP model with analytical formulae, and estimated accurately the computational cost taking into account load distributions caused by data layout and process mapping. Some knowledge for optimization of block algorithm has been obtained. Our estimations have been verified through numerical experiments on three different distributed memory parallel computers. 相似文献